Polymer could cut fuel cell costs.
by Walter, Patrick
A conducting polymer grown on the same material used to make
waterproof raincoats could provide a cheap and plentiful alternative to
platinum in fuel cells.
Most hydrogen fuel cells currently rely on platinum to catalyse the
splitting of hydrogen into protons and electrons at one electrode, and
to reduce oxygen so the hydrogen protons and electrons can combine to
form water at the other electrode.
The researchers from Monash University in Australia created a
polymer-based electrode that can reduce oxygen as effectively as
platinum. The group coated a porous Goretex membrane with an ultra-thin,
40nm, layer of gold to improve the electrode's conductivity. They
then 'grew' layers of poly(3,4-ethylenedioxythiophene) (PEDOT)
on the Goretex using vapour phase polymerisation. The electrode operated
for 1500 hours without any deterioration in the material (Science 2008,
321, 671).
[ILLUSTRATION OMITTED]
Using a layer of gold to improve the electrode's conductivity
is, author Douglas MacFarlane admits, swapping one expensive metal for
another. But he adds that the amount of gold used is miniscule and they
are already working to replace it with other, more common metals. And
the monomer of PEDOT is readily available and could be much cheaper if
it were rolled-out in large scale applications.
Chris Rhodes, an independent energy consultant, says it is a
'nice piece of work'. However, he adds, 'This is not a
solution but one of so many technological "solutions" that
cannot be implemented fast enough to replace or cheapen the cost of
oil-based transport.'
MacFarlane also concedes that they have only solved half the
problem. A hydrogen electrode that does not rely on platinum is still
needed, which he describes as 'a big challenge'.
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