Entrepreneur: Start & Grow Your Business

Polymer could cut fuel cell costs.


by Walter, Patrick
Chemistry and Industry • August 11, 2008 • Hydrogen power

A conducting polymer grown on the same material used to make waterproof raincoats could provide a cheap and plentiful alternative to platinum in fuel cells.

Most hydrogen fuel cells currently rely on platinum to catalyse the splitting of hydrogen into protons and electrons at one electrode, and to reduce oxygen so the hydrogen protons and electrons can combine to form water at the other electrode.

The researchers from Monash University in Australia created a polymer-based electrode that can reduce oxygen as effectively as platinum. The group coated a porous Goretex membrane with an ultra-thin, 40nm, layer of gold to improve the electrode's conductivity. They then 'grew' layers of poly(3,4-ethylenedioxythiophene) (PEDOT) on the Goretex using vapour phase polymerisation. The electrode operated for 1500 hours without any deterioration in the material (Science 2008, 321, 671).

[ILLUSTRATION OMITTED]

Using a layer of gold to improve the electrode's conductivity is, author Douglas MacFarlane admits, swapping one expensive metal for another. But he adds that the amount of gold used is miniscule and they are already working to replace it with other, more common metals. And the monomer of PEDOT is readily available and could be much cheaper if it were rolled-out in large scale applications.

Chris Rhodes, an independent energy consultant, says it is a 'nice piece of work'. However, he adds, 'This is not a solution but one of so many technological "solutions" that cannot be implemented fast enough to replace or cheapen the cost of oil-based transport.'

MacFarlane also concedes that they have only solved half the problem. A hydrogen electrode that does not rely on platinum is still needed, which he describes as 'a big challenge'.


COPYRIGHT 2008 Society of Chemical Industry Reproduced with permission of the copyright holder. Further reproduction or distribution is prohibited without permission.
Copyright 2008 Gale, Cengage Learning. All rights reserved. Gale Group is a Thomson Corporation Company.
NOTE: All illustrations and photos have been removed from this article.



Copyright © Entrepreneur.com, Inc. All rights reserved. Privacy Policy